PART
– (10 x 2 = 20 marks)
1.
What
is heat?
2.
Prove
that cp-cv=R.
3.
State
zeroth law of thermodynamics. What is its application?
4.
Deduce
the relation between the COP of heat pump and refrigerator.
5.
What
is meant by thermodynamic temperature scale? How do you device such scale?
6.
What
do you understand by pure substance? Give some typical examples.
7.
What
is critical point? What are the properties of water at critical point?
8.
What
are the unique features of van der Waals equation of state?
9.
What
is compressibility factor? What does it signify? What is its value for van der
Waals gas at critical point?
10. What is dew
point temperature? How is it related to dry bulb and wet bulb temperature at
the saturation condition?
PART B – (5 x
16 = 80 marks)
11. (i) Prove that
internal energy is a property? (4)
(ii) 1 kg of gas at 1.1 bar, 27°C is compressed to
6.6 bar as per the law pu 1.3=
const. Calculate work and heat transfer, if
(1)
When
the gas is ethane (C2H6)
with molar mass of 30 kg/k mol and cp of 2.1 kJ/kg K.
(2)
When
the gas is argon (Ar) with molar mass of 40 kg/k mol and cp of 0.52
kJ/kg K.
(12)
12.
(a) (i) “Two reversible adiabatic lines
cannot intersect”. Is this statement true or false? Justify the answer. (4) (ii)A reversible engine operates
between a source at 972°C and two sinks, one at 127°C and another at 27°C. The
energy rejected is same at both the sinks. What is the ratio of heat supplied
to the heat rejected? Also calculate the efficiency. (12)
(Or)
(b) (i) what
are the conditions for reversibility? (2)
(ii) Differentiate between heat pump and refrigerator. (2)
(iii) 50kg of water is at 313 K and enough ice at -5°C is mixed
with water in an adiabatic vessel such that at the end of the process all the
ice melts and water at 0°C is obtained. Find the mass of ice required and the
entropy change of water and ice. Given cp of water = 4.2 kJ/kg-K, cp
of ice = 2.1 kJ/kg-K and latent heat of ice = 335 kJ/kg.
(12)
13.(a)(i) Draw the p-T diagram of a pure substance
and label all the phases and phase changes.
(4)
(ii) What
do you understand by dryness fraction? What is its importance? (2)
(iii) A
rigid tank of 0.03 m3 capacity contains wet vapour at 80 kPa. If the
wet vapour mass is 12 kg, calculate the heat added and the quality of the
mixture when the pressure inside the tank reaches 7 MPa. (10)
(Or)
(b)(i) What are the major problems of Carnot
vapour cycle? (2)
(ii) What
are the methods for improving the performance of Rankine cycle (2)
(iii) Steam
enters the turbine at 3 MPa and 400°C and is condensed at 10 kPa. Some quantity
of steam leaves the turbine at 0.6 MPa and enters open feed water heater.
Compute the fraction of the steam extracted per kg of steam and cycle thermal
efficiency. (12)
14.(a)(i) Write down the Dalton’s law of
partial pressure and explain its importance.(6)
(ii) 0.45 kg of CO and 1 kg air is
contained in a vessel of volume 0.4 m3 at 15°C. Air has 23.3% of O2 and
76.7% of N2 by mass. Calculate the partial pressure of each constituent and
total pressure in the vessel. Molar masses of CO, O2 and N2 are
28,32 and 28 kg/k mol. (10)
(Or)
(b)(i) What is the use of Clapeyron equation?
And write it down for liquid-vapour region. (6)
(ii) Explain the flow process of a real
gas through a throttle value. Drive the expression for Joule Thomson
coefficient and deduce its value an ideal gas.(10)
15.(a)(i) Differentiate between Dry bulb temperature and wet bulb
temperature. (4)
Wet bulb depression and
dew point depression (4)
(ii) Air at 16°C and 25% relative
humidity passes through a heater and then through a humidifier to reach final
dry bulb temperature of 30°C and 50% relative humidity. Calculate the heat and
moisture added to the air. What is the sensible heat factor? (8)
(b)(i) In an adiabatic mixing of two
streams. Derive the relationship among the ratio of mass of streams, ratio of
enthalpy change and ratio of specific humidity change. (8)
(ii) Saturated air at 20°C at a rate of 1.167 m3/Sec
is mixed adiabatically with the outside air at 35°C and 50% relative humidity
at a rate of 0.5 m3/sec. Assuming adiabatic mixing condition at 1
atm, determine specific humidity, relative humidity,dry bulb temperature and
volume flow rate of the mixture.
(8)
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