Answer All questions
PART A – (10×2=20 marks)
1.      State the first law for a closed system undergoing a process and a cycle?
2.      Why does free expansion have zero work transfer?
3.      What is thermal energy reservoir? Explain the term source and sink?
4.      What is reserved heat engine?
5.      What is meant by dryness fraction of steam?

6.      Draw the standard Rankine cycle on p –v and T- s coordinates?
7.      What is Joule – Thomson co efficient? Why it is zero for an ideal gas?
8.      What is the law of corresponding states?
9.       What is Amagat’s Law?
10.  What is sensible heating?
PART- B – (5×16=20 marks)
11.  a) A gas under goes a thermodynamic cycle consisting of the following process:
i)                    Process 1-2: Constant pressure p1 = 1.4 bar, V1 = 0.028 m3, W12 = 10.5 kJ.
ii)                  Process 2-3: Compression with pV = constant, U3 = U2.
iii)                Process 3-1: Constant Volume, U1 – U3 = 26.4kJ.
There are no significant changes in K.E and P.E
1)      Sketch the cycle on a pV diagram.
2)      Calculate the network for the cycle in KJ.
3)      Calculate the heat transfer for process 1-2.
4)      Show that £Qcycle =  £Wcycle
OR

b) A turbine operating under steady flow condition receives steam at the flow state pressure 13.8 bar specific volume 0.143m3KJ internal energy 250kJ/Kg velocity 30 m/s the state of the steam leaving the turbine is pressure 0.35 bar specific volume 4.37 m3KJ internal energy 2360kJ/Kg Velocity 90 m/s heat is last to the surrounding at the rate 0.25kJ/s. if the rate of steam flow is 0.38kJ/s. what is the power developed by the turbine?
         12.     a)   A reversible heat engine operates between two reservoirs at temperature of 6000C and 400C. The engine drives a reversible refrigerator    which operates between reservoirs at the temperature of  400C and - 200C. The heat transfer to the heat engine is 2000kJ and the network output for the combined engine refrigerator is 360kJ. Calculate the heat transfer to the refrigerator and the net heat transfer to the reservoir at 400C.
OR
                b) Two kg of air at 500kPa, 800C expands adiabatically in a closed system until its volume is doubled and its temperature becomes equal to that of the surroundings which is at 100 kPa, 50C. For this process determine
            i) The maximum work
            ii) The change in availability and the irreversibility
13  a)   A vessel of volume 0.04m3 contains a mixture of saturated water and saturated steam at a temperature of 2500C. The mass of the liquid    present is 9kg. Find the pressure, the mass, the specific volume, the enthalpy and entropy and the internal energy of the mixture.
OR
b) A steam power plant operates in a simple ideal Rankine cycle between the pressure limits of 3Mpa and 50Mpa. The temperature of the steam at the turbine inlet is 3000C and the mass rate of steam through the cycle is 35kg/s. Show the cycle on a Ts diagram with respect to saturation lines and determine
i) The thermal efficiency of the cycle and
ii) The net power output of the power plant
14.  a) Derive any three of the Maxwell relations?
OR
b)  Determine the pressure of nitrogen gas at T = 175 K and v = 0.00375m3/kg on the basis of
i) The ideal gas equation of state
ii) The van der Waals equation of state.
The van der Waals constants for nitrogen are a= 0.175m6.kPa/kg2 , b = 0.00138m3/kg
15. a)  An engine ideal air standard diesel cycle has the compression ratio 15 and heat transfer 1400kJ/kg. Find the pressure and temperature at the end of the each process if the inlet conditions are 280K and 1.1 bar. Find also the air standard efficiency and mean effective pressure.
OR
b) Atmospheric air at 1.0132 bar has a DBT of 300C and WBT of 250C.
  compute
i)                    The partial pressure of water vapour
ii)                  Specific humidity
iii)                The dew point temperature
iv)                The relative humidity
v)                  The degree of saturation
vi)                The density of air in the mixture
vii)              The density of vapour in the mixture and

viii)            The enthalpy of the mixture. Use the thermodynamic tables only.